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Nonparametric analysis of a complete state of water modelling systems of neutral amino acids

The data obtained by the device about indicators propuskanija and their dispersions on various frequencies of the Ik-spectrum of investigated ranges were treated by the computer programs, allowing to estimate system as a whole.

Fig.

17 Change of a dispersion of indicators propuskanija Ik-radiations of modelling solutions alanina concentration from 10-1М to 10-16 M in a range: 1710-1610 sm-1 of 1600-1535 sm-1 of 1543-1425 sm-1

76

LL

The information is based on results of correlation and discriminant analysis of results under preliminary chosen standard (bidistillirovannaja water), with the subsequent comparison of complete indicators of a state of system by criteria Mahalanobisa and Bartletta.

It is defined, that for Gli criterion Mahalanobisa variates wavy with achievement of the maximum values at delution in 1016. Solution delutions It is scarlet lead to gradual decrease in criterion Mahalanobisa for which the minimum value of the investigated size is defined at the maximum delution.

It is established, that initial concentrations, and as solutions of identical degree of delution (10-5, 10-14,10-16) have raznonapravlennoe change

Sizes of criterion Mahalanobisa (fig. 19), that most likely is bound to inverse action of acids on a structural state of a water basis of solutions.

At the further investigation phase relative analysis of dispersions of quotients propuskanija separate investigated ranges of an infra-red spectrum, in the samples having similar high or low criteria Mahalanobisa that can give more detailed identification of states of water systems of investigated materials arising in the presence of various quantities is carried out.

Analysis of dispersions of Item P of solutions, with maximum value of criterion Mahalanobisa has allowed to establish for solutions Gli (delutions in 109 and 1016 times authentic distinctions of the given indicator in all ranges of lengths of waves (fig. 20).

For solution It is scarlet (delutions 105 and 1014) there are authentic distinctions in all investigated ranges of the Ik-spectrum, except range of 1127-1057 sm-1 where are defined libratsionnye fluctuations of moleculas of water (fig. 21).

Fig. 19 Influence glitsina and alanina (delution of solutions of 1 M in 101-1016раз) on size of fluctuation of indicators propuskanija Ik-radiations of flakes of water

Fig. 20 Comparison of dispersions of quotients propuskanija solutions glitsina in delution of 109 and 1016 times by Fisher's one-dimensional criterion

Fig. 21 Comparison of dispersions of quotients propuskanija solutions alanina in delution 105 and 1014раз by Fisher's one-dimensional criterion

Aanaliz dispersions of Item P of solutions with the minimum value of criterion Mahalanobisa has shown, that for Gli (fig. 22) and It is scarlet (fig. 23) absence of authentic differences in all ranges, except 1543-1425 sm-1 and 1710-1610 sm-1, 1067-930 sm-1 accordingly is revealed. The given ranges are characteristic for communications of bunches-CH2,-CH3; deformation and libratsionnyh fluctuations of moleculas of water

Fig. 22 Comparison of dispersions of quotients propuskanija solution glitsina in delution 105 and 1012раз by Fisher's one-dimensional criterion

Fig. 23 Comparison of dispersions of quotients propuskanija solution alanina in delution 104 and 1012раз by Fisher's one-dimensional criterion

By results of experiences it is possible to draw a conclusion on influence of small quantities of neutral amino acids on a dispersion propuskanija Ik - a spectrum of flakes of modelling solutions: Gli is more awake in the attitude to a water basis of the solutions (at the smaller maintenance is capable to invoke the big changes) that can be caused absence of the hydrocarbonic assistant in frame of the given molecula and decrease in waterproof influence.

5.2

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Scientific source Butavin Nikita Jurevich. INFLUENCE ENDO - And EKZOGENNYH FACTORS ON the INFRA-RED SPECTRUM of WHEY of BLOOD of TEENAGERS. The dissertation on competition of a scientific degree of a Cand.Biol.Sci. Tver, 2014. 2014

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